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Journal of Lipid Research, Vol. 10, 589-592, September 1969
Copyright © 1969 by Lipid Research, Inc.

Mass spectral discrimination between monoenoic and cyclopropanoid, and between normal, iso, and anteiso fatty acid methyl esters

Iain M. Campbell and John Naworal

Department of Biochemistry and Nutrition, Graduate School of Public Health, University of Pittsburgh, Pittsburgh, Pennsylvania 15213

Measurement of the ratio of the intensity of the parent molecular ion to that of the parent molecular ion minus 32 (the mass of methanol) can distinguish between monoenoic and cyclopropanoid fatty acid methyl esters with the same carbon number. A similar technique can be used to distinguish between isomeric normal, iso, and anteiso fatty acid methyl esters.

Supplementary key words intensity ratios • GLC-mass spectrometry • isomers

Submitted on March 26, 1969
Accepted on June 4, 1969


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