J. Lipid Res.
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Journal of Lipid Research, Vol 27, 352-353, Copyright © 1986 by Lipid Research, Inc.

ARTICLES

A simple method for the synthesis of cholesteryl ethers

PK Sripada

A novel method for the synthesis of cholesteryl ethers is described. The mesylates of fatty alcohols were treated with the sodium salt of cholesterol in toluene at 80 degrees C in the presence of anhydrous dimethyl formamide. The hexyl, tetradecyl, and oleyl cholesteryl ethers were synthesized in yields varying between 55 and 70%. Tritiated cholesteryl oleyl ether was also synthesized in good chemical (45%) and radiochemical (45%) yields.
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Copyright © 1986 by the American Society for Biochemistry and Molecular Biology.