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Journal of Lipid Research, Vol. 9, 137-139, January 1968
Copyright © 1968 by Lipid Research, Inc.

New method for the reductive ozonolysis of double bonds in monoenoic fatty acid methyl esters

S. Ramachandran , P. Venkata Rao , and David G. Cornwell

Department of Physiological Chemistry, The Ohio State University, Columbus, Ohio 43210

Unsaturated methyl esters were cleaved to aldehydes and aldehydo-esters by ozonolysis followed by reduction with dimethyl sulfide after conversion to hydroperoxides. Cleavage products were identified by thin-layer chromatography and quantified by temperature programmed gas-liquid chromatography.

Supplementary key words ozonolysis-reduction • unsaturated methyl esters • ozonides • hydroperoxides • aldehydes • aldehydo-esters • dimethyl sulfide • dimethyl sulfoxide • thin-layer chromatography • gas-liquid chromatography

Submitted on August 28, 1967
Accepted on October 9, 1967


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