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Journal of Lipid Research, Vol. 9, 270-275, March 1968
Copyright © 1968 by Lipid Research, Inc.

Mass spectrometry of derivatives of cyclopropene fatty acids

N. Kim Hooper and John H. Law

Department of Biochemistry, University of Chicago, Chicago, Illinois 60637

Diketo fatty acids prepared by ozonization of cyclopropene fatty acids have been separated and purified by chromatographic techniques. Mass spectra of esters of these compounds and of methanethiol adducts of cyclopropene acid esters are reported and interpreted. Location of the ring from examination of mass spectra of these derivatives appears to be a straightforward matter.

Supplementary key words cyclopropene fatty acids • diketo fatty acids • thiol adducts • mass spectrometry

Submitted on August 31, 1967
Accepted on November 1, 1967

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